Why is Gold Yellow? The Chemistry of GOLD

Chemistry of GOLD jameskennedymonash v2
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Why is Gold yellow? Special relativity causes length contractions and time dilations in objects that travel at speeds approaching the speed of light. The valence electrons of large atoms such as gold have such high energies that their speeds actually approach the speed of light—and the relativistic effects on those electrons can become quite large.

Special relativity changes the energy levels of the 5d orbital in a gold atom so that the energy difference between 5d and 6s orbitals equals the energy of a ‘blue’ photon. Gold thus absorbs blue light when electrons are elevated from the 5d to the 6s orbitals, while other metals do not. These special relativistic changes to the energy levels of atomic orbitals are slightly different for each element.

Relativistic contractions on gold’s valence electrons (the 6s subshell) pull the 6s electron very close to the nucleus. Being closer to the nucleus makes the 6s electron less accessible to any potential reactants. Special relativity is not only the reason for gold’s yellow colour but also for its very low reactivity! ●

4 thoughts on “Why is Gold Yellow? The Chemistry of GOLD

  1. I’m way behind you I was led to believe that colour is given to a substance by the light it reflects. So a red object reflects red and absorbs the rest. In green light red looks black. If we are talking about periodic tables why is sulphur yellow ? Such a simple element ? I don’t really know. In the natural world complex organics are often coloured such as chlorophyll once again they reflect that wavelength of visible light. Copper has a beautiful brown golden colour but most metals are silver. Phosphorous at least in one form is red.

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    1. Read Kurt Nassau’s book “The fourteen causes of color” to see just how complicated color is. Saying gold is yellow because it reflects yellow light is like saying lead is heavy because it has a lot of mass. The real question is, why does gold (or sulfur) reflect yellow? It turns out the reasons are completely different for gold and sulfur. And topaz and sunflowers have still other causes. Which in turn are nothing like the causes of yellow colors at sunset.

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