I’ve had the pleasure of hosting the second season of Sincerely, Chemicals. It’s just me and a camera this time. Very simple.
Subscribe to the Sincerely, Chemicals YouTube channel to receive a new video each week.
I’ve had the pleasure of hosting the second season of Sincerely, Chemicals. It’s just me and a camera this time. Very simple.
Subscribe to the Sincerely, Chemicals YouTube channel to receive a new video each week.
Bisphenol A, or BPA, is used to line food cans and also to make strong plastic baby bottles. Eating large amounts of canned food – particularly canned soups or drinking hot liquids from baby bottles – can result in elevated amounts of BPA being detected in people’s urine. BPA acts as an estrogen mimic – albeit a very weak one – and some research has suggested a link between large doses of BPA and an increase of blood pressure. While this does sound worrying, remember that the dose is extremely important and that the molecules of BPA that do leech into food are too few to have any measurable effect.
The United States Food and Drug Administration (the FDA) conducted a four-year review of over 300 scientific studies and concluded that the traces of BPA that do migrate into canned food are so tiny that they have no effect on human health.
The decision to abandon the use of BPA in baby bottles was therefore based on public pressure not based on safety or on scientific evidence.
The science never suggested there was any safety concern with BPA.
Don’t forget to like and subscribe for more videos from Sincerely, Chemicals.
Each year, the VCAA subtly upgrades the VCE Chemistry data book. Each year, I print it and annotate it to show students the wealth of useful information hidden within it (most of which, is in plain sight).
This year, the VCAA has changed some “constants” and added some interesting functional groups to the spectroscopy tables. Smaller things are changed, too. All the protons in the 1H NMR table are now in bold; not just the ambiguous ones.
Start using this annotated version of the data book for your year 11 and year 12 chemistry homework exercises. While you can’t take this annotated version into the final examination (or into most SACs), seeing the annotations frequently throughout the two years will help you find things faster in the final examination.
Do you have feedback? Any comments? Do you require 1-to-1 chemistry tutoring? Email me at firstname.lastname@example.org and I’ll get back to you personally.
I started a YouTube channel called Sincerely, Chemicals. It’s inspired by the workshops I’ve been running since 2017 so you can now review the content at home.
Video 2 is below. It’s called “Are Organic Products Safer?”… you already know the answer, but play the 2-minute video to find out why.
If you like these videos, please leave a comment, like and subscribe. That way, I might be encouraged to make more 🙂
P.S. I hope you like the cartoons!
The Naturalness Fallacy is my latest book in the chemophobia series. It’s a quick read that introduces the causes, effects and solutions to the chemophobia problem.
Download this free book as a PDF here.
After several hurdles, I’m happy to announce that Fighting Chemophobia is now available on Amazon in both paperback and Kindle editions for international delivery. Amazon.com and three other independent online book vendors have signed up to stock Fighting Chemophobia.
Buy your copy by clicking the links below – or search Amazon.com or your Kindle device for Fighting Chemophobia to download the book.
Signed copies are of this new third edition are of course still available via this website. Click the PayPal link below to order your signed copy.
I’ve been working on some exciting things in the last few months. Watch this space for teasers.
The second batch of Fighting Chemophobia books are finished! After a long search, we have finally found two great companies for printing and distribution in China. Dianzan design and printing company has laid the book out with great care and precision and turned Fighting Chemophobia into an excellent-quality product in both hardback and paperback editions. The 80 gsm Dowling paper feels great, and there are even some full-page colour images scattered throughout the book. Shunfeng Express is handling cheap, quick shipping and is currently achieving 2-day deliveries within China. They predict 7-day delivery times internationally.
This second batch is higher quality than the first. I’m sure you’ll love what these people have produced.
Working with a publisher could have saved me the search for an editor, a printer, a distributor, a marketer and a translator. Self-publishing has been more rewarding in this regard: not only have I selected the people I’ve worked with to bring this book to completion but I’ve probably learned more this way about the process of writing, editing, printing, binding, marketing and distributing a book than if a publisher had handled the entire process on my behalf.
You can buy your signed copy of the second batch of Fighting Chemophobia using the PayPal link below. Click subscribe on this page to receive future (approximately fortnightly) email updates.
Chemophobia is an irrational fear of chemicals. It includes the fear of sugar in food, formaldehyde in shampoo and aluminium in vaccines. Fitness bloggers, quack doctors and even small cosmetic companies take advantage of these quirks to sell fake-natural products at elevated prices. Almost always, the same people who spread a fear of ‘chemicals’ also have ‘chemical-free’ products for sale.
Some companies sell “natural”, “organic” and “chemical-free” products to combat the supposed onslaught of chemical pollution in conventional consumer products. Most of these alternative products are no less synthetic, and no safer, than conventional versions despite commanding much higher prices.
Chemophobia is spreading despite our world becoming a cleaner, safer place. People are becoming healthier, and product safety regulations are becoming stricter. The supposed onslaught of chemicals that these special interest groups describe simply isn’t happening.
Perpetrators of chemophobia create unnecessary guilt, stress and anxiety as consumers worry about making the right choices for their family. Consumers are the victims in this battle as pro-natural and anti-natural businesses spread fear about each other’s products.
This book analyses psychological quirks, evolved millennia ago, that prime us to fall victim to chemophobic ways of thinking such anorexia, a fear of vaccines, a fear of fluoridation or a dangerous fear of synthetic medicines. It explores how consumers, teachers, doctors, lawmakers and journalists can fight chemophobia by tackling the social issues that underpin it.
Unlike purple and pink pigments, which were rare and expensive enough to be reserved for royalty and high-ranking clergy, yellow pigments were abundant throughout ancient history. Yellow ochre, a powdery mixture of iron oxides, has been used in cave paintings around the world for up to 80,000 years and was still being used by artists in the early nineteenth century. Saffron and turmeric were also used as yellow dyes throughout ancient history. Vincent van Gogh was using mineral yellow pigments such as cadmium yellow and chrome yellow in his mid-nineteenth century paintings. By the mid-nineteenth century, people looking for yellow pigments already had plenty of options. Despite there being no pressure from consumers for a new yellow dye, chemists trying to replicate the fame and fortune that mauveine brought to William Perkin in 1856 were experimenting eagerly in pursuit of that goal.
In 1861, Mêne was reacting aniline with cold nitrous acid to produce a diazonium salt solution. He then added more aniline to the resulting salt solution and shook the flask vigorously and noticed a yellow precipitate formed at the bottom of the flask, which would later become known as ‘aniline yellow’ – the first ‘azo dye’. 
The reaction mixture must be kept cool (at around 5 °C) because different temperatures cause different products to form. If the same reactants are mixed warm, then smelly liquid phenol and inert nitrogen gas are formed, both of which are colourless, and neither of which are useful as pigments!
At the time, the ‘aniline yellow’ powder he discovered was considered useless because it didn’t dissolve in water. However, it did dissolve very well in oil. The dye eventually gained some niche uses as a microscopy stain (like fuchsine) but was never utilised by the garment or pigment industry.
After staying relatively unused for over a hundred years, aniline yellow left an unfortunate legacy for itself by becoming the culprit molecule in the Spanish ‘Toxic Oil scandal’ of 1981. A batch of Spanish rapeseed oil had been denatured (deliberately adulterated) with 2% aniline yellow so the company could report it as “machine oil” and take advantage of certain tax breaks. One local refinery obtained the denatured rapeseed oil and attempted to remove the aniline yellow dye so they could sell it on as “pure olive oil” on the market for profit. They sold the oil around much of north-western Spain in unlabelled 5-litre plastic containers.
The first casualty was an eight-year-old boy who died upon arrival at a hospital in Madrid on May 1st, 1981. The rest of his family then presented with an unusual set of symptoms: headache, fever, itchy scalp, lethargy and interstitial lung disease. The hospital diagnosed the family with “atypical pneumonia” and treated them all with antibiotics but they showed little improvement. 
Across Spain, 20,000 patients presented with similar symptoms within one month of the incident. Thinking that an unexplained pneumonia outbreak was unfolding, a children’s hospital in Madrid conducted a randomised, double-blind controlled clinical trial on the effectiveness of the antibiotic erythromycin, which is particularly effective on infections of the respiratory system.  Unfortunately, they found no difference in recovery or mortality rates between the treated group and the control group and decided to keep looking for potential treatments.
Attempting all avenues, the researchers conducted lifestyle surveys on many patients, which included (among many other things) questions about cooking oil. Sadly, even though the source of the problem was staring them in the face, the results of the oil usage survey questions came back “inconclusive”. 
A baby ultimately solved the puzzle. Prognosis for young children was generally worse than for adults after they contracted the strange set of symptoms. Oddly, babies under six months were unaffected even if the entire rest of the family had presented with the pneumonia-like symptoms. Their infants were completely symptom-free. When one baby did get sick, however, this prompted deep and urgent questioning of the parents involved to find out what they did differently from others. One unusual aspect of the baby’s upbringing was that the baby’s grandmother had been ‘supplementing’ baby’s formula powder with cooking oil that was sold in an unlabelled 5-litre plastic container. 
Spanish government agencies acted quickly. The Ministry of Health and Consumer Affairs issued a recall of all oil sold in unlabelled plastic bottles within 40 days of the first casualty reporting with symptoms (the 8-year-old boy). Rates of patients presenting with symptoms of Toxic Oil Syndrome, as it would later be called, plummeted after the recall was announced on June 10th, 1981.
The aniline yellow had all been removed. The problem was a side-reaction, completely unknown to the scientists who were purifying the “machine oil”, that formed a new, harmful molecule that was large enough to escape their detection methods.
The molecule responsible for Toxic Oil Syndrome is called “OO PAP” in scientific literature. Visual inspection of OO PAP’s structure reveals that it’s quite simply an olive oil triglyceride molecule (triolein) with one of its three fatty acid tails replaced with a large aniline group.  When the rapeseed oil was adulterated with 2% aniline yellow to disguise it as “machine oil”, some of the aniline yellow molecules didn’t just blend in with the oil but reacted chemically with it to make OO PAP molecules. ITH, the company who sold the de-adulterated product as “pure olive oil”, was likely unaware of this chemical reaction, and therefore (we assume) also unaware of the poisonous OO PAP that had formed in the oil. While ITH successfully removed the aniline yellow, they failed to remove the OO PAP molecules, which escaped their filtration techniques.  Sadly, hundreds of people died and 20,000 more were made ill from OO PAP poisoning, and financial damage was estimated by El País newspaper to be 2 billion pesetas (around 16 million US dollars today).  Just like the scandal of the pink fuchsine socks, government and industry were forced to work together to respond quickly to a growing public crisis.
Every chemical – regardless of whether it’s found naturally or created synthetically – has the potential to be beneficial, harmful or harmless depending on the dosage and the way that it’s used. Aniline yellow, like all other chemicals, is incredibly useful when used correctly. It’s a fantastic microscopy stain but totally unsuitable for culinary use.
Today, people use aniline yellow to dye specimens for viewing under a light microscope. Aniline yellow’s dangers are stated clearly on its safety data sheets: handling it today requires training, permits, safety glasses, gloves and a lab coat to avoid all contact with skin and eyes. Now that chemistry has given us a better understanding of the aniline yellow, nobody dare use it to dye foodstuffs. 
 Paz, Manuel Posada de la. 2001. “Toxic Oil Syndrome: The Perspective after 20 Years.” Epidemiologic Reviews 231-247.
 Gelpí, Emilio. 2002. “The Spanish Toxic Oil Syndrome 20 Years after Its Onset: A Multidisciplinary Review of Scientific Knowledge.” Environmental Health Perspectives 457-464.
 Flores, Juan Casado. 1982. “Sindrome Toxico en Niños por Consumo de Aceites Vegetales: Modelo Clinico de la Enfermedad, en la Fase Aguda.” Pediatrika 22-26.
 Flores, Juan Casado. 1982. “Síndrome toxico por consumo de aceite adulterado. Una encuesta alimentaria esclarecedora.” Pediatrika 17-20.
 Paz, Posada de la. 1999. “Epidemiologic evidence for a new class of compounds associated with toxic oil syndrome.” Epidemiology 130-134.
 El País. 1981. “2.000 millones de pesetas costará al Insalud la asistencia a los enfermos a causa del aceite.” El País 15.
 Southern Biological. 2009. “Material Safety Data Sheet: Fuchsine.” Southern Biological. 08. Accessed 12 19, 2016. http://file.southernbiological.com/Assets/Products/Chemicals/Stains_and_Indicators-Powders/SIP4_6-Basic_Fuchsin/SIP4_6_MSDS_2009_Basic_Fuchsin.pdf.
The “deficit model” is a widely criticized theory that suggests that people who harbor attitudes of negativity or indifference towards science (in this case, chemistry) do so because they are uninformed about the topic (Chinese: 无知).
People’s misinformation might come from a lack of interest, a lack of exposure or an experience of poor science outreach in the past, where incorrect messages were delivered.
The “deficit model” stipulates that if people knew more about science, they’d naturally become more interested in it. Unfortunately, it doesn’t always seem to work, and the ‘model’ is subjected to routine criticism.
Critics of the “deficit model” tend to advocate solutions that involve dialogue (rather than monologue) with the public. Dialogue works better when the particular public audience in question has pre-existing views about the scientific topic being discussed (called ‘affected/partisan’ public groups).
There are four main types of ‘public’ audiences. The table below summarizes each of these types and how to engage with them, and is adapted from Canek Phillips report from 2013.
The general public consists of people with diverse views that represent a cross-section of society. In a group, these views cancel out somewhat, hiding the deviation of views. The “deficit model” of monologue delivery is an effective way to engage such a group.
The pure public is a group of people who have no pre-existing ideas about the topic being discussed. The “deficit model” can engage these audiences as well.
The affected public can only be engaged if their pre-existing views are acknowledged and respected beforehand. Dialogue is an excellent way of doing this. Examples of dialogue-based approaches include science shops, public hearings, citizen judies, stakeholder consultations and focus groups.
The partisan public is sometimes led by charismatic leaders or lobby groups. Their views might have been shaped by influential figures (e.g. Mercola, Food Babe) and the pre-existing views (misconceptions) delivered in this way need to be debunked through respectful dialogue rather than monologue.
In short, before telling your audience something, find out whether they have any pre-existing ideas about that topic. If they don’t, then go ahead with a monologue delivery. If they do, then launch a two-way discussion with them, in which you listen and respect their views. Only then, will they respect your opinion as well. ♦
The wines your great-grandchildren might one day drink on Mars will soon be coming to a bottle near you. Ava Winery is a San Francisco-based startup creating wines molecule by molecule, without the need for grapes or fermentation. With complete control over the chemical profile of the product, Ava’s wines can be created safely, sustainably, and affordably, joining the food technology revolution in creating the foods of the future.
For Ava, foods in the future will be scanned and printed as easily as photographs today. These digital recreations will be more than mere projections; they will be true chemical copies of the originals, capturing the same nutritional profiles, flavors, and textures of their “natural” counterparts. Our canvas will be macronutrients like starches and proteins; our pixels will be flavor molecules. Future generations won’t distinguish “natural” from “synthetic” because both will simply be considered food.
Consider ethyl hexanoate, although scary-sounding it is the very chemical that gives pineapples their characteristic smell and also fruity wines a tropical note. From pineapples, or indeed other organisms, ethyl hexanoate can be extracted much more efficiently. By sourcing more efficient producers of each of hundreds of different components, wines can be recreated as their originals.
Future generations won’t distinguish “natural” from “synthetic” because both will simply be considered food.
In fact, by eliminating the variability of natural systems as well as potential environmental contamination, this digitized future of food can increase the safety, consistency, and nutritional profile of foods. Such food products can reduce overall land and resource use and be less susceptible to climate fluctuations. Indeed this future will see significant reductions in the costs of food production as the cost of the raw ingredients shifts to more efficient sources of each molecule.
So why wine?
We knew there would be a controversial love/hate relationship with our mission to build wine molecule by molecule. To the elite who value the high-end wine experience, our molecularly identical creation of the $10,000+ bottle of 1973 Chateau Montelena will be a mockery; but to the public, the $10,000 turned $20 bottle will be a sensation. To the purists who still believe organic is the only way to eat or drink healthily, our wine will get “some knickers in knots”; but to the nonconformists, our wine will be a contemporary luxury made by contemporary technology.
In short, wine is just the beginning. Soon, Ava hopes to build more food products molecule by molecule further blurring these lines between natural vs. synthetic while simultaneously making luxury items available for all. With our groundwork, the Star Trek future of food might be closer than we thought.
In 2014, I soon followed up with podcasts, radio appearances, press interviews, a T-shirt Store and twelve more fruit ingredient labels. I’ve done six more customised fruit ingredients labels for private clients. The images have since appeared in textbooks, corporate promotional material, YouTube videos, T-shirts, mugs and aprons.
Momentum built in 2015. Parodies emerged online, and a copycat image appeared in one Chemistry textbook. I started writing about chemophobia and consulting with experts on how to address the issue. In short, it’s very, very complicated, and has deep evolutionary origins. I set a goal to understand chemophobia and provide a roadmap to tackle it effectively.
In 2016, my voluminous OneNote scribblings turned into a book. I have a first draft saved on OneDrive (thank you for keeping it safe, Microsoft) and I’ll be proofreading it on an long-haul intercontinental flight for you later today.
I promise that my book “Fighting Chemophobia” will contain the following:
This “Fighting Chemophobia” book is for:
To get your hands on a copy, subscribe to this blog for email updates. Just click ‘Follow’ somewhere on this page (its location depends on which device you’re using).
I promise that throughout 2017, you’ll receive teasers, snippets and discarded book fragments via this blog to get you excited.
This post concludes the Periodic Table Smoothie experiment.
Recall that we’ve just finished adding one mole of nitrogen gas and created a bizarre boron polymer at the bottom of our vessel. The temperature was 350 °C and the pressure in our vessel was 891 kPa.
Today, we’re going to add 1.00 mole of oxygen gas, stand back and observe.
This is disappointing news.
Many of the substances in our vessel react (more accurately, explode) in the presence of oxygen but the ignition temperature for all of those explosions to take place is at least 500 °C. The temperature of our vessel is set at just 350 °C. At this temperature, nothing would actually happen.
There’s not enough activation energy to break bonds in the reactant particles in order to get the reaction started. We call this activation energy (EA) in chemistry. If we were to add a source of excessive heat (e.g. a matchstick), the vessel would explode.
If we did, the following reactions would happen:
Enough of these reactions – particularly the first three – are sufficiently exothermic to trigger a chain reaction – at least up to the reaction of oxygen with beryllium carbide. The vessel would bang, explode, and shatter. The helium would float away, dangerous lithium amide would fly out sideways, and polyborazine powder, whatever that is, would land on the floor.
Let’s not ignite our experiment – not yet.
|Substance||Amount in mol|
Pressure: 891 kPa (higher than before due to the addition of nitrogen gas)
Temperature: 350 °C (vessel is still being maintained at constant temperature)
Oxygen was relatively uneventful. Let’s add fluorine and see what happens.
The following three reactions would all occur as 1.00 mole of fluorine gas is added:
These two products are quite interesting:
When 1.00 mole of neon gas is added, the total pressure inside the vessel increases but no reaction occurs. The concentrations of all the other gases present are unaffected.
That concludes our Periodic Table Smoothie experiment. The most interesting conclusion was the discovery of polyborazine, the bizarre solid that collected at the bottom of the vessel.
Also of interest was how easily we created ammonia, one of the simplest of biological compounds, just by mixing elements together. Could the compounds necessary for life be so easy to create that their existence is an inevitable consequence of the Big Bang? Is life inevitable? If the Big Bang were to happen all over again, would life occur? And would it look any different?
These lies include well-meaning simplifications of the truth, mistakes in the textbook, and, in a few extreme cases, blatant falsehoods.
This book isn’t a criticism of the VCE Chemistry course at all. In fact, I just want to highlight the sheer complexity of Chemistry and the need to make sweeping generalisations at every level so it can be comprehensible to our students. This is a legitimate practice called constructivism in pedagogical circles. (Look that up.)
Many of these ‘lies’ taught at VCE level will be debunked by your first-year chemistry lecturers at university.
Here’s a preview of some of the lies mentioned in the book. Check out all 50 by clicking the download link at the bottom of the page.
The content you’re learning now is probably not as true as it seems. Chemistry is a set of models that explain the macro level sometimes at the expense of detail. The more you study Chemistry, the more precise these models become, and they’ll gradually enlighten you with a newfound clarity about the inner workings of our universe. It’s profound.
Rules taught as ‘true’ usually work 90% of the time in this subject. Chemistry has rules, exceptions, exceptions to exceptions, and exceptions to those – you’ll need to peel pack these layers of rules and exceptions like an onion until you reach the core, where you’ll find Physics and Specialist Maths.
Enjoy this book. I hope it emboldens you to question everything you’re told, and encourages you to read beyond the courses you’re taught in school.
Yes, you did. I use the term “redox” to refer to all of the following chapters in Heinemann Chemistry 2, which you will have learned at the end of Term 3 (September).
The VCAA has consistently used redox to discriminate which schools and students have the self-discipline required to keep studying at the end of the year. Studies show that redox is taught at a time when student motivation is at its minimum: energy levels are low, emotions are high, and graduation is just over the horizon. Many schools and students gloss over these topics because they’re running out of time, any many students think they’ve grasped the topic – when they’ve actually grasped misconceptions instead.
LIE #1: The polarities switch during recharge
Nope. The polarities never switch. It’s the labels of ‘anode’ and ‘cathode’ that switch because the electrons are flowing the other way through the external circuit. Polarity is permanent.
LIE #2: Hydrogen fuel cells don’t emit any greenhouse gases
Wrong. They emit H2O, which is a powerful greenhouse gas. If you don’t believe that the VCAA can be this pedantic, think again. Read their 2015 Examiners Report here.
LIE #3: Each mole of electrons forms 1 mol Ag, 2 mol Cu or 3 mol Al in a cell
Wrong again. If you look at the half-equations, you’ll see that each mole of electrons actually forms 1 mol Ag, 1⁄2 mol Cu or 1⁄3 mol Al. That’s why I teach “1, 1⁄2 and 1⁄3 moles” instead of the typical “1, 2, 3 moles” rule.
LIE #4: Temperature increases the rate of reaction in electroplating
Wrong! Remember that Faraday’s first law states that m ∝ Q. Because Q = I×t, only those two things – current and time – can affect the mass deposited at the cathode.
LIE #5: Electrons always leave the anode and go towards the cathode
Wrong again. Electrons go RACO: to see what that means, download the posters above. This question appears in recent versions of Chemistry Checkpoints. Give it a try.
LIE #6: The cathode is always positive
Ask your teacher.
LIE #7: Ions flow one way in the salt bridge
Nope. Anions always migrate to the anode; and cations always migrate to the cathode.
LIE #8: KOHES always works for balancing half-equations
KOHES only works for cells with acidic electrolytes. For cells with alkaline electrolytes, which sometimes appear in VCAA papers despite not being in the study design (see page 46 here), you’ll need to use KOHES(OH). Here’s KOHES(OH) explained:
LIE #9: I can balance an unbalanced redox equation by putting numbers in the equation
Don’t be fooled by this one! The ONLY way to balance an unbalanced redox equation successfully is to do the following:
That’s a lot of work but it’s the only way to do it successfully. If you try to ‘cheat’ by just writing numbers (molar coefficients) in front of the reactants and products, you’ll find that the charges don’t add up, and you’ll get zero marks for the question.
LIE #10: I can break up polyatomic ions to make balancing half-equations easier
Nope! You’re only allowed to separate aqueous species in a half equation or an ionic equation. Because the Mn and O are actually bonded together in a polyatomic ion, you’ll need to write this:
Instead of this:
If in doubt, keep it intact and it’ll cancel out by the end if it’s a spectator ion.
LIE #11: The two reactants that are closest together on the electrochemical series react
Not always true. Use SOC SRA instead, which is explained in the posters above. Still struggling? Ask your teacher or tutor for help.
LIE #12: Oxidants are all on the top of the electrochemical series
They’re actually on the left, and all the reductants can be found on the right side of each half equation in the electrochemical series. There is no top/bottom divide on the electrochemical series: only a left/right divide of oxidants/reductants.
Surround yourselves with truthful redox revision using these 17 free Redox posters. I’ve had these up around the whiteboard for a few weeks now – they’re a constant reminder to students that redox has many ideas that are always true.
One more tip: print and laminate an electrochemical series (available here) so you can annotate it during dozens of practice dozens without wasting paper. Good luck!